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Metal-Organic Chemical Vapor Infiltration

 

Potential applications include:

  • Protection of C/SiC, SiC/SiC, and C/C composites

  • Protective overlayers on fibers/fiber coatings (carbon-based T-300, SiC, and oxide fibers can be deposited directly on woven fabrics and preforms

  • Protective overcoats on thermal barrier coatings

  • Conformal hermetic coverage for MEMS devices and miniature components used in biomedical, semiconductor, photonic, and other industrial processes

  • Passivation and low-friction surface modifications of metals and alloys

Applied Thin Films, Inc. introduces a low-cost & high throughput metal-organic chemical vapor infiltration (MOCVI) process for conformal deposition of amorphous alumina and alumina-based coatings. Dense, uniform, hermetic, highly conformal, and smooth films are deposited at relatively low temperatures (400–700ºC). The process can accommodate complex-shaped objects with submicron-sized holes/features. A variety of substrates including fibers, woven fabrics, multilayer fabric preforms, metal foils and alloys, and other proprietary materials have been coated. Coating thickness can be varied from 50nm to 10 microns or more with deposition rates greater than 1 mm/minute.

The process allows for deposition at high rates (over 1µm/minute) with a high degree of uniformity and smoothness. The reactor configuration can be scaled up easily to accommodate large substrates. The use of inexpensive precursor and exhaust treatment makes this process economical with minimal environmental impact and low maintenance. The MOCVI process is also suitable for chemical manipulation/tailoring of coatings such that doped layers can be grown to enhance desirable properties.

 

Protective alumina films deposited directly on woven fabrics to provide protection to fiber and enhance toughness and durability of ceramic matrix composites.

TEM micrograph of an as-deposited alumina coating on a woven ceramic fabric. The alumina coating is dense and pin-hole free.

SEM micrograph of a 10 micron thick MOCVI alumina coating on steel foil.

Excellent coverage demonstrated on a 6-ply Nextel preform (thickness around filaments ranged from 0.3 – 1.5 mm).

Applied Thin Films, Inc.
Copyright © 2007  Last modified: 09/06/07
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Evanston  •  IL 60201  •  USA

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